Letter: Ionmolecule reactions of the benzoyl ion [C

₆H₅CO]⁺ with compounds containing the amine functional group in a quadrupole ion trap

Full-text article (40 kB)
(subscribers only)

Buy article on-line for £11.75
(get immediate access)

Eur. J. Mass Spectrom. 4, 103 - 106 (1998)

Letter: Ionmolecule reactions of the benzoyl ion [C₆H₅CO]⁺ with compounds containing the amine functional group in a quadrupole ion trap

Brian L. Williamson and Colin S. Creaser^*
Department of Chemistry and Physics, Nottingham Trent University, Clifton Lane, Nottingham NG11 8NS, UK.

ABSTRACT:

The benzoyl ion, [C₆H₅CO]⁺, reacts within the time and pressure regimes of the quadrupole ion trap with compounds containing an amine functional group to yield characteristic [M + 105]⁺, [M NH₂]⁺ and [C₆H₅CONH₃]⁺ product ions. Product ion distributions are determined by the amine environment, making it a potentially useful probe for establishing the presence and chemical environment of amine groups.

Keywords: Ionmolecule reactions, benzoyl, ion, chemical ionisation, quadrupole ion trap, mass spectrometry.

You can now buy this paper on-line in PDF format; it costs only £11.75. Just click on the BUY on-line button. You can pay on-line through a secure server and get access immediately.