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Eur. J. Mass Spectrom. 5, 309 - 317 (1999) |
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Generation of three isomers of C7H in the gas phase. A joint experimental and theoretical study | ||
Suresh Dua, John H. Bowie and Stephen J. Blanksby |
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ABSTRACT: | ||
Three anion isomers of formula C7H have been synthesised in the mass spectrometer by unequivocal routes. The structures of the isomers are [HCCC(C2)2], C6CH and C2CHC4. One of these, [HCCC(C2)2], is formed in sufficient yield to allow it to be charge stripped to the corresponding neutral radical. | ||
Keywords: circumstellar molecules, three isomers of C7H, neutral HC2C(C2)2 |
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