Volume 9 Issue 4 2003 Table of Contents

*Indicates author to whom correspondence should be addressed

Pages ix - x

Foreword

Pascal Gerbaux
Laboratoire de Chimie Organique, Université de Mons-Hainaut, Avenue Maistriau 19, B-7000 Mons, Belgium

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DOI: 10.1255/ejms.562

Pages 223 - 235

Charge exchange in tandem mass spectrometry: dissociative single electron capture by doubly-charged toluene cations

Dorina Fati and Bernard Leyh*,b
Laboratoire de Dynamique Moléculaire, Département de Chimie, Bâtiment B6c, Université de Liège, B-4000 Sart-Tilman, Belgium. E-mail:

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DOI: 10.1255/ejms.546

Pages 237 - 234

Translational to vibrational energy conversion during surface-induced dissociation of n-butylbenzene molecular ions colliding at self-assembled monolayer surfaces

Sung-Chan Jo and R. Graham Cooks*
Department of Chemistry, Purdue University, West Lafayette, IN 47907, USA. E-mail:

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DOI: 10.1255/ejms.554

Pages 245 - 255

Is allylphosphine a carbon or a phosphorus base in the gas phase?

Maria del Carmen Sicilia,a Otilia Mó,a Manuel Yáñez,a Jean-Claude Guillemin,b Jean-François Galc and Pierre-Charles Mariac
aDepartamento de Química, C-9. Universidad Autónoma de Madrid. Cantoblanco, 28049-Madrid, Spain
bLaboratoire de Synthèse et Activation de Biomolécules, UMR-6052 CNRS, ENSCR, 35700 Rennes, France
cChimie des Matériaux Organiques et Métalliques, Université de Nice-Sophia Antipolis, Parc Valrose, 06108 Nice Cedex 2, France

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DOI: 10.1255/ejms.558

Pages 257 - 266

A quantum chemical study of the protonation of phenylphosphine and its halogenated derivatives

Pham-Cam Nam,a,b Pascal Gerbauxc,d and Minh Tho Nguyena,*
aDepartment of Chemistry, University of Leuven, Celestijnenlaan 200F, B-3001 Leuven, Belgium. E-mail:
bFaculty of Chemical Engineering, University of Danang, Vietnam
cLaboratoire de Chimie Organique, Universit de Mons-Hainaut, Avenue Maistriau 19, B-7000 Mons, Belgium

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DOI: 10.1255/ejms.557

Pages 267 - 277

Stereochemical interactions in ammonium dications, hypervalent diammonium cation-radicals and ammonium radicals. A B3-MP2 computational study

Frantiaek Turecek
Department of Chemistry, Bagley Hall, Box 351700, University of Washington, Seattle, WA 981, USA

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DOI: 10.1255/ejms.548

Pages 279 - 285

Ionmolecule reactions of [C, H3, S]+ ions and evidence for long-lived triplet CH3S+

Mariano Teruel,a,c Patricia R.P. de Moraes,b Luciano A. Xavier,b José M. Riverosb*
aUniversidad Nacional de Córdoba, Facultad de Ciencias Químicas, INFIQC, RA-5000 Córdoba, Argentina
bInstitute of Chemistry, University of São Paulo, Caixa Postal 26077, São Paulo, Brazil, CEP 05513-970. E-mail:

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DOI: 10.1255/ejms.553

Pages 287 - 294

Potential role of methyl-radical adducts with carbon dioxide in the Martian atmosphere

Detlef Schröder,* Marija Semialjac and Helmut Schwarz

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DOI: 10.1255/ejms.552

Pages 295 - 304

The kinetic method as a structural diagnostic tool: ionized α-diketones as loosely one-electron bonded diacylium ion dimers

Eduardo C. Meurer,a Fabio C. Gozzo,a R. Augustib and Marcos N. Eberlin*a
aState University of Campinas UNICAMP, Institute of Chemistry CP6154, 13083-970 Campinas, SP Brazil. E-mail:
bFederal University of Minas Gerais UFMG, Department of Chemistry, CP 702, 31270-901 Belo Horizonte, MG Brazil

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DOI: 10.1255/ejms.563

Pages 305 - 318

Gas-phase bimolecular reactions between ·CH2(CH2)nC+=O distonic ions and pyridine: a combined experimental and theoretical study

Pascal Gerbaux,* Pascale Wantier, Micheline Bury, Claude De Meyer, Daniel Finet and Yves Van Haverbeke
Organic Chemistry Laboratory, University of Mons-Hainaut, 19 Avenue Maistriau, B-7000 Mons, Belgium. E-mail:

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DOI: 10.1255/ejms.551

Pages 319 - 326

Reactions of CH3CHO·+ and of CH3COH·+ with water upon Fourier transform ion cyclotron resonance conditions

H. Nedev, G. van der Rest, P. Mourgues* and H.E. Audier
Laboratoire des Mécanismes Réactionnels, UMR CNRS, Ecole Polytechnique, F-91128, Palaiseau, France. E-mail:

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DOI: 10.1255/ejms.564

Pages 327 - 341

A ring walk of methylene groups in toluene radical cations. An extension of the toluene-cycloheptatriene rearrangement of aromatic radical cations. Theory and experiment

Hans-Friedrich Grützmacher and Natascha Harting

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DOI: 10.1255/ejms.565

Pages 343 - 350

Reactions of the ionized enol tautomer of acetanilide: elimination of HNCO via a novel rearrangement

Lisa N. Heydorn,a Lynn M. Carter,b Richard D. Bowenb and Johan K. Terlouwa*
aDepartment of Chemistry, McMaster University, 1280 Main St W., Hamilton, ON, L8S 4M1, Canada. E-mail:
bDepartment of Chemical and Forensic Sciences, University of Bradford, Bradford, West Yorkshire BD7 1DP, UK

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DOI: 10.1255/ejms.550

Pages 351 - 360

Fragmentation mechanisms of protonated benzylamines. Electrospray ionisation-tandem mass spectrometry study and ab initio molecular orbital calculations

Sophie Bourcier and Yannik Hoppilliard*
DCMR, UMR CNRS 7651, Ecole Polytechnique, 91128 Palaiseau Cedex, France. E-mail:

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DOI: 10.1255/ejms.566

Pages 361 - 376

The gas-phase basicity and proton affinity of 1,3,5-cycloheptatrieneenergetics, structure and interconversion of dihydrotropylium ions

Jean-Yves Salpin,a,b,c Michael Mormann,a Jeanine Tortajada,b Minh-Tho Nguyenc and Dietmar Kucka*
bUMR CNRS 8587 "Analyse et environnement", Bâtiment des Sciences, Université d'Évry Val d'Essonne, Boulevard Fran!ois Mitterrand, F-91025 Évry CEDEX, France
cDepartment of Chemistry, University of Leuven, Celestijnenlaan 200 F, B-3001 Leuven, Belgium

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DOI: 10.1255/ejms.556

Pages 377 - 390

Gas-phase reactivity of silver and copper coordinated monosaccharide cations studied by electrospray ionization and tandem mass spectrometry

Laurence Boutreau, Emmanuelle Léon,a Jean-Yves Salpin,a Badia Amekraz,b Christophe Moulinb and Jeanine Tortajadaa*
aLaboratoire Analyse et Environnement, UMR CNRS 8587, Université d'Evry, Val d'Essonne Bât. des Sciences, Boulevard François Mitterrand, 91025 Evry Cedex, France. E-mail
bCEA SACLAY, DEN/DPC/SECR, Laboratoire de Spéciation des radionucléides et des Molécules, Bâtiment 391, 91191 Gif/Yvette Cedex, France

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DOI: 10.1255/ejms.567

Pages 391 - 402

Gas-phase basicity of glycine, alanine, proline, serine, lysine, histidine and some of their peptides by the thermokinetic method

G. Bouchouxa and J-Y. Salpinb
aLaboratoire des Mécanismes Réactionnels, UMR CNRS 7651, Ecole Polytechnique, 91128 Palaiseau Cedex, France
bLaboratoire Analyse et Environnement, UMR 8587, Bâtiment des Sciences, Université d'Evry, boulevard F. Mitterrand, 91025 Evry cedex, France

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DOI: 10.1255/ejms.568

Pages 403 - 407

Electrospray mass spectrometry of 2-aminotroponimines and 2-aminotropones

Rosa M. Claramunt,a Dionisia Sanz,a Marta Pérez Torralba,a José Elguero,a Pierre Sanchez,b Christine Enjalbal,b Jean Martinezb and Jean-Louis Aubagnac*,b
aDepartamento de Química Orgánica y Biología, Facultad de Ciencias, UNED, Senda del Rey 9, E-28040 Madrid, Spain
bUMR5810, Laboratoire des Aminoacides, Peptides et Protéines, Universités de Montpellier I et II, F-34095 Montpellier Cedex 5, France

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DOI: 10.1255/ejms.560

Pages 409 - 420

The application of liquid chromatography-electrospray ionization mass spectrometry and collision-induced dissociation in the structural characterization of acylated flavonol O-glycosides from the seeds of Carrichtera annua

Filip Cuyckens,a Abdelaaty A. Shahat,a Hilde Van den Heuvel,a Khaled A. Abdel-Shafeek,b Moustafa M. El-Messiry,b Medhat M. Seif-El Nasr,b Luc Pieters,a Arnold J. Vlietincka and Magda Claeysa*
aUniversity of Antwerp (UA), Department of Pharmaceutical Sciences, Universiteitsplein 1, B-2610 Antwerp, Belgium. E-mail:
bDepartment of Pharmaceutical Sciences, National Research Centre, 12311 Dokki, Cairo, Egypt

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DOI: 10.1255/ejms.559


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